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where the subscript "cr" denotes the critical point Differentiation of Eq (341) yields expressions for both derivatives, which may be equated to zero for P = PC,T = T,, and V = V, The equation of state may itself be written for the critical conditions These three equations contain five constants: PC,V,, T,, a(T,), and b Of the several ways to treat these equations, the

7 ~M Abbott, AIChE J, vol 19, pp 596601, 1973; Adv in Chern Series 182, K C Chao and R L Robinson, Jr, eds, pp 47-70, Am Chem Soc, Washington, DC, 1979

atomicSet.Commit( )

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most suitable is elimination of Vc to yield expressions relating a(Tc) and b to PCand T, The reason is that PCand Tc are usually more accurately known than V, An equivalent, but more straightforward, procedure is illustrated for the van der Waals equation Since V = Vcfor each of the three roots at the critical point,

Equation (340) expanded in polynomial form becomes:

atomicSet.Rollback( )

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Recall that for a particular substance parameter a in the van der Waals equation is a constant, independent of temperature Term-by-term comparison of Eqs (A) and (B) provides three equations:

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Solving Eq (D) for a , combining the result with Eq (E), and solving for b gives:

Substitution for b in Eq (C) allows solution for V,, which can then be eliminated from the equations for a and b:

The release of ADONET included with Version 35 of the NET Framework (that s the version that comes with Visual Studio 2008) includes a new component: the ADONET Entity Framework Part entity-relationship modeling tool, part code generator, this new technology helps you craft logical data views of the data stored in your relational database or other data source The Entity Framework lets you design three types of objects based on your stored data: entities (similar to tables), relationships (database joins), and entity sets (related entities) Each type is represented by objects that expose the members of your core database in a more programmable fashion For instance, you can design an entity object representing a table in your database, and the object s members can represent the fields in a single record So what, you say It sounds like the same features built into ADO.

Although these equations may not yield the best possible results, they provide reasonable values which can almost always be determined, because critical temperatures and pressures (in contrast to extensive PV T data) are often known, or can be reliably estimated Substitution for V, in the equation for the critical compressibility factor reduces it immediately to: 3 z = -pcvc - " - RT, 8 A single value for Z,, applicable alike to all substances, results whenever the parameters of a two-parameter equation of state are found by imposition of the critical constraints Different values are found for different equations of state, as indicated in Table 31, p 93 Unfortunately, the values so obtained do not in general agree with those calculated from experimental values of Tc, PC,and Vc;each chemical species in fact has its own value of Z, Moreover, the values

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