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Further variation is possible in the polymer structure and properties by using mixtures of the appropriate reactants such that the polymer chain can have different R and R0 groups. Thus polyamide structures of types XXXV and XXXVI are possible variations on structures XXXIII and XXXIV, respectively. A polymer such as XXXV or XXXVI has two different repeat units and is referred to as a copolymer; the process by which it is synthesized is

The 1960s public was ready, as Bob Moog would discover, for electronic synthesizers. Things were happening within corporations and universities research teams were designing both musical as well as purely experimental electronic instruments (the latter wonderfully exemplified by the Michel Waisvisz/Geert Hamelberg crackle box of the late 1960s, an instrument later developed at Steim in Amsterdam that, although from the start designed to do what it does and therefore not a circuit-bent or chance-designed instrument, still uses body contacts for control). But something very important more important to us, in fact was also happening outside the theory-guided teams and institutions. It was happening way down at street level. A totally new approach to design was being launched. Renegade electronics insurgence was at hand. The threshold of invention, placing susceptible mid-1960s electronic circuits and music-curious humans upon the stage simultaneously, was at work creating its usual synchronicity of planetwide discovery. All over the world, lone wolves like me were discovering that the accidental howling one encountered upon touching the live circuits of battery-powered audio electronics was musical.

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referred to as a copolymerization. Polymers with structures XXXIII and XXXIV, each containing a single repeat unit, may be referred to as homopolymers to distinguish them from copolymers.

The trouble was largely of foreign origin England had experienced very little of a boom in the late 1920 s The American stock market collapse, the rash of bank failures in America and Europe, the rush for liquidity, and the liquidation of foreign balances all put unbearable pressure on the newly convertible pound The bank rate was pushed up from 21 2 % to 6% in 1931, and consols declined 10 points, to 491 2, to yield 505% still well above 1920 low prices In late 1931, the pound was set loose from gold, and monetary policy was reversed In 1932, the bank rate was brought down to its traditional low of 2% It was held there, except for a brief rise in 1939, for eighteen years The open market rate of discount declined in 1931 1932 from 588% to 068%, and stayed down.

Different types of copolymers are possible with regard to sequencing of the two repeating units relative to each other. Thus a copolymer with an overall composition indicated by XXXV could have the alternating copolymer structure shown in XXXV, in which the R, R0 , R00 , and R000 groups alternate in that order over and over again along the polymer chain; or the block copolymer structure XXXVII, in which blocks of one type of homopolymer structure are attached to blocks of another type of homopolymer structure; or the statistical copolymer structure, in which there is an irregular (statistical) distribution of R and R00 groups as well as R0 and R000 groups along the copolymer chain. Similarly, one can have alternating, block, and statistical copolymers for the overall composition XXXVI.

For the statistical copolymer the distribution may follow different statistical laws, for example, Bernoullian (zero-order Markov), rst- or second-order Markov, depending on the speci c reactants and the method of synthesis. This is discussed further in Secs. 6-2 and 6-5. Many statistical copolymers are produced via Bernoullian processes wherein the various groups are randomly distributed along the copolymer chain; such copolymers are random copolymers. The terminology used in this book is that recommended by IUPAC [Ring et al., 1985]. However, most literature references use the term random copolymer independent of the type of statistical distribution (which seldom is known). The alternating and statistical copolymer structures can be symbolized as

The 21 2% consols rose in a few months from 491 2, or 505%, to 781 2, or 318% their high price since 1912 This was a price rise of 58% In 1932, the giant 5% War Loan was redeemed and successfully converted into an issue of War Loan 31 2s at a price of 99, to yield 354% The new loan was not redeemable until 1952, and, in the ancient tradition, it was perpetual unless the government chose to redeem England was again in a period of easy money Long yields did not decline to the lows of the late nineteenth century, but short-term interest rates got down to new lows The economic and political environments, however, were sadly different from what they had been in the easy-money decades of the nineteenth century.

where A and B represent two different repeating units. Different block copolymers are distinguished by the number of blocks per molecule, for example

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